Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1305026 | Inorganic Chemistry Communications | 2006 | 4 Pages |
Abstract
Complex fac-[RuCl3(NO)(P–N)] was synthesized from [RuCl3(H2O)2(NO)] in methanol solution under reflux. The orange solid obtained was characterized by NMR (31P{1H}, 1H, 13C) and, cyclic voltammetry, ESI-MS, IR, elemental analysis and X-ray diffraction structure determination. The 31P{1H} reveals the presence of singlet at 36 ppm. IR N–O stretching as KBr pellets or CH2Cl2 solution presented 1866 cm−1 and 1872 cm−1, respectively.
Graphical abstractThe first P–N containing {RuNO}6 was obtained starting from [RuCl3(H2O)2(NO)]. The fac-isomer was isolated from the reaction and was characterized by NMR (31P, 1H, 13C), ESI-MS, elemental analysis and cyclic voltammetry.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Deividi A. Cavarzan, Fábio R. Caetano, Lincoln L. Romualdo, Fábio B. do Nascimento, Alzir A. Batista, Javier Ellena, Andersson Barison, Márcio P. de Araujo,