A novel selenium–molybdenum oxide chain inserted with copper (II) complex: Synthesis, structure, and magnetic property

A one-dimensional polyoxomolybdate compound inserted with both selenite and copper (II) complex, [(bipy)CuSeMo3O12]n, has been hydrothermally synthesized and structurally characterized. This is the first example that polyoxomolybdate framework modified by both selenite and transition metal complex. A strong ferromagnetic interaction occurred in this compound due to magnetic coupling between copper (II) centers.

Graphical abstractA one-dimensional polyoxomolybdate compound inserted with both selenite and copper (II) complex, [(CuO3bipy)2(SeO3)2(Mo6O18)] (bipy = 2,2’-bipyridine), has been hydrothermally synthesized and structurally characterized. This is the first example of polyoxomolybdate framework modified by both selenite and transition metal complex.Figure optionsDownload full-size imageDownload as PowerPoint slide