Article ID Journal Published Year Pages File Type
1305145 Inorganic Chemistry Communications 2006 4 Pages PDF
Abstract

One-dimensional copper(II) polymers [(Cu4L2)(NO3)4]n (1) and [(Cu4L2)Cl4]n (2) (H2L = salicylaldehyde-2-pyridinecarboxyl-hydrazone) were achieved via self-assembly. The Cu⋯Cu separations were ca. 2.90 and 4.75 Å for the phenoxide oxygen bridged pair and the N–N bridged pair with antiferromagnetic spin exchanges between Cu(II) ions.

Graphical abstractTwo new one dimensional copper(II) polymers based on tetranuclear units was achieved via self-assembly from N3O2 pentadentate ligand and structurally characterized.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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