Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1305145 | Inorganic Chemistry Communications | 2006 | 4 Pages |
Abstract
One-dimensional copper(II) polymers [(Cu4L2)(NO3)4]n (1) and [(Cu4L2)Cl4]n (2) (H2L = salicylaldehyde-2-pyridinecarboxyl-hydrazone) were achieved via self-assembly. The Cu⋯Cu separations were ca. 2.90 and 4.75 Å for the phenoxide oxygen bridged pair and the N–N bridged pair with antiferromagnetic spin exchanges between Cu(II) ions.
Graphical abstractTwo new one dimensional copper(II) polymers based on tetranuclear units was achieved via self-assembly from N3O2 pentadentate ligand and structurally characterized.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yan Bai, Dongbin Dang, Xin Cao, Chunying Duan, Qingjin Meng,