| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1305194 | Inorganic Chemistry Communications | 2016 | 5 Pages |
•Five novel lanthanide coordination polymers were synthesized and structurally characterized.•Eu-compound shows a warm white light emission upon excitation.•Magnetic measurement indicates weak ferromagnetic coupling existing between adjacent Tb3+ centers.
Five two-dimensional lanthanide coordination polymers: [Ln2(TDA)3(bipy)2(H2O)2]·bipy·2H2O (Ln = Nd (1), Sm (2), Eu (3), Tb (4), Yb (5), TDA = thiophene-2,5-dicarboxylic acid anion, bipy = 2,2′-bipyridine) were fabricated and structurally characterized. Compounds 1–5 are isostructural belonging to the triclinic system with space group P-1. Luminescence analyses were performed on coordination polymers containing Eu3 + and Tb3 +, and compound 3 shows a warm white light emission upon excitation.
Graphical abstractFive novel lanthanide coordination polymers: [Ln2(TDA)3(bipy)2(H2O)2]·bipy·2H2O (Ln = Nd (1), Sm (2), Eu (3), Tb (4), Yb (5), TDA = thiophene-2,5-dicarboxylic acid anion, bipy = 2,2′-bipyridine) were fabricated and structurally characterized. Luminescence analyses suggest that compound 3 shows a warm white light emission upon excitation.Figure optionsDownload full-size imageDownload as PowerPoint slide
