| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1305218 | Inorganic Chemistry Communications | 2016 | 4 Pages |
•A novel 1D lead(II) coordination polymer containing anthracene chromophore was synthesized.•Surface photovoltage spectroscopy and luminescent properties of the compound were studied.•The 1D molecular nanowires with a diameter of 1.22 nm were observed in the compound.
A novel 1D lead(II) coordination polymer containing anthracene chromophore through the employment of hydrothermal techniques by using 9-anthracenecarboxylic acid and PbI2, [Pb(9-aca)2(H2O)2] (1) (9-acaH = 9-anthracenecarboxylic acid) has been synthesized and structurally characterized by X-ray single-crystal diffraction as well as by powder X-ray diffraction and elemental analysis. In compound 1, each PbO8 polyhedron is linked to each other by oxygen atoms from 9-acaH ligand to form a 1D molecular nanowire with a diameter of 1.22 nm. Surface photovoltage spectroscopy (SPS) and field-induced surface photovoltage (FISPS) of compound 1 indicate that it possesses positive SPV response in the range of 300–800 nm and shows p-type semiconductor characteristic. Luminescent properties of compound 1 reveal that the compound exhibit strong luminescence, ascribed to the charge transfer of anthracene chromophore and the semiconductor 1D Pb2O2 chain.
Graphical abstractA novel 1D lead(II) coordination polymer containing anthracene chromophore has been synthesized. In compound 1, each PbO8 polyhedron is linked to each other by oxygen atoms from 9-acaH ligand to form a 1D molecular nanowires with a diameter of 1.22 nm. Surface photovoltage spectroscopy (SPS) and field-induced surface photovoltage (FISPS) of compound 1 indicates that it possesses positive SPV response in the range of 300–800 nm and shows p-type semiconductor characteristic. Luminescent properties of compound 1 reveal that the material exhibit strong luminescence, ascribed to the charge transfer of anthracene chromophore and the semiconductor 1D Pb2O2 chain.Figure optionsDownload full-size imageDownload as PowerPoint slide
