| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1305260 | Inorganic Chemistry Communications | 2016 | 5 Pages |
•A new 3D luminescent Cd(II) metal-organic framework has been obtained and characterized.•It exhibits detection of TNP with high selectivity and recyclability.•It also exhibits quantitative detection of the ultralow temperature.•It can be applied as the first potential dual-functional luminescent sensing material for TNP and temperature.
A novel 3D Cd(II) MOF, {[Cd(Ccbp−)(4.4′-bpy)·H2O]·(ClO4−)·2H2O} (1), (Ccbp− = 3-carboxy-1-(4-carboxybenzyl)pyridin-1-ium, 4.4′-bpy = 4.4′-bipyridine), has been successfully synthesized and characterized. Complex 1 possesses a 3D 4-fold interpenetrating dia network with a pyridine cation basic skeleton. This Cd-MOF 1 can be applied as the first potential dual-functional luminescent sensing material for high selective and recyclable sensing of 2,4,6-trinitrophenol and quantitatively detecting the ultralow temperature from 10 to 60 K.
Graphical abstractA novel luminescent Cd(II) metal-organic framework with 3D 4-fold interpenetrating dia network has been successfully synthesized and characterized. This Cd-MOF 1 can be applied as the first potential dual-functional luminescent sensing material for high selective and recyclable sensing of 2,4,6-trinitrophenol and quantitatively detecting the ultralow temperature from 10 to 60 K.Figure optionsDownload full-size imageDownload as PowerPoint slide
