| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1305286 | Inorganic Chemistry Communications | 2016 | 4 Pages |
•One thricyanometallate based chain {FeIII2FeII} has been synthesized.•Ferromagnetic interaction dominates in them.•The complex exhibits the coexistence of the SCM and spin-glasses behavior.
A cyano-bridged ferromagnetic {FeIII2FeII} alternating chain {[FeIII(pzTp)(CN)3]2[FeII(imidazole)(H2O)]}·3H2O (1) (pzTp = tetrakis(pyrazolyl)borate) was synthesized via rational design. Crystal structure analysis studies demonstrated that complex 1 had a one-dimensional double zigzagging chain-like structure. Magnetic measurements showed that ferromagnetic interactions dominate in 1 and the AC magnetic susceptibility revealed two limit regimes in accordance with the single chain magnet and spin-glass behavior.
Graphical abstractOne cyano-bridged based {FeIII2FeII} chain has been synthesized by utilizing the thricyanometallate precursors [FeIII(pzTp)(CN)3]− with the Fe2 + ion and imidazole as an auxiliary ligand. The complex exhibits the coexistence of the single chain magnet and spin-glass behavior.Figure optionsDownload full-size imageDownload as PowerPoint slide
