Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1305482 | Inorganic Chemistry Communications | 2015 | 4 Pages |
•Mg/Co–Al/Fe–CO3 LDHs were synthesized by coprecipitation reaction method.•The Mg–Al LDHs samples with onefold Co2 + or Fe3 + doping are paramagnetic.•Room temperature ferromagnetism can be obtained by Co2 + and Fe3 + codoping.•The specific effects and mechanism of Co2 + and Fe3 + doping were discussed in detail.
Mg/Co–Al/Fe–CO3 layered double hydroxides were synthesized by coprecipitation reaction method. According to powder X-ray diffraction (Cu–Kα) and scanning electron microscopy, all the samples exhibit hydrotalcites with layered double structure. Onefold Co2 + or Fe3 + doping does not show ferromagnetism. Room temperature ferromagnetism can be obtained by Co2 + and Fe3 + codoping, on the condition that more than 50% of Mg2 + and Al3 + are substituted by Co2 + and Fe3 +, respectively. The coaction of different magnetic interactions leads the macroscopic ferromagnetism of the samples. The ferromagnetic coupling of Co2 +–O2−–Co2 + results in the ferromagnetism of brucite-like layers and the antiferromagnetic coupling of Co2 +–O2−–Fe3 + enhances the magnetism of the interlayers.
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