Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1305738 | Inorganic Chemistry Communications | 2011 | 5 Pages |
Abstract
⺠Under the catalysis of 1,10-phenathroline (phen), two clusters [M'S4Cu4(SCN)2 (dppm)3 ] (M' = Mo, W) were synthesized. ⺠The method using phen as the catalysis was confirmed to be an effective strategy of synthesizing new metal clusters. ⺠The possible catalysis mechanism of phenathroline is discussed. ⺠The skeletons of Mo/W-Cu/Ag clusters are affected by the coordinated anions and the coordination number of metal atom.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Qiong-Hua Jin, Ye-Lan Xiao, Ke-Yi Hu, Zhong-Feng Li, Rong Wang, Cun-Lin Zhang,