Assembly of a water-insoluble strontium metal–organic framework with luminescent properties

A new strontium metal–organic framework, [Sr2(BTEC)(H2O)4]∙2H2O (1) (H4BTEC = benzene-1,2,4,5-tetracarboxylic acid), has been successfully synthesized by mixing the starting reagents. The single-crystal structure analysis showed that compound 1 displayed three-dimensional structures containing inorganic motifs with two-dimensional layers pillar-connected through organic linkers and forming water-coordinated neutral framework. Further studies revealed that compound 1 was insoluble in water and that it emitted strong luminescence at approximately 437 nm after dehydration.

Graphical abstractA new strontium metal-organic framework was synthesized by mixing the starting. The extended 3D framework contains two-dimensional inorganic layers connected through organic linkers and forming neutral frameworks.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► A new strontium metal-organic framework was synthesized by mixing the starting reagents. ► Strontium metal-organic framework is an extended 3D framework. ► Strontium metal-organic framework is insoluble in water. ► Strontium metal-organic framework emits strong luminescence at around 437 nm after dehydration.