| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1305752 | Inorganic Chemistry Communications | 2011 | 4 Pages |
A novel inorganic–organic hybrid compound [Mn(teta)][Mn(teta)(H2O)2]2{V18O42(Cl)}·8H2O (1) (teta: triethylenetetramine) has been hydrothermally synthesized and characterized by TGA, IR and XPS analysis. Its structure is determined by single-crystal X-ray diffraction analysis. Compound 1 exhibits a rare 2-D planar square lattice (sql net), which was constructed by the well known {V18O42} cluster as node and two distinct Mn (II) complexes, [Mn(teta)] and [Mn(teta)(H2O)2], as single/double μ2-bridging linkers. This type sql net with two distinct Mn (II) complexes is the first example found in polyoxovanadates. The magnetic study shows that there exists antiferromagnetic interaction within 1.
Graphical abstractA novel inorganic–organic hybrid solid [Mn(teta)][Mn(teta)(H2O)2]2{V18O42(Cl)}·8H2O (1) (teta: triethylenetetramine) has been synthesized. It features 2-D planar network constructed by {V18O42(Cl)} cluster and two distinct Mn (II) complexes: [Mn(teta)] and [Mn(teta)(H2O)2] as single/double μ2-bridging linkers, which is the first example found in polyoxovanadates.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► 1 was constructed by {V18O42(Cl)} cluster and distinct Mn (II) complexes. ► 1 contains two distinct Mn (II) complexes as single/double μ2-bridging linkers. ► The sql net with two distinct Mn (II) complexes is rare in polyoxovanadates.
