Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1305761 | Inorganic Chemistry Communications | 2011 | 4 Pages |
Two new pincer bis (carbene) ligands and corresponding ruthenium (II) carbonyl iodide complexes have been synthesized and characterized. The structures of complexes 3 and 4 have been determined by X-ray crystallography. Complexes 3 and 4 have been proved to be efficient catalysts in the transfer hydrogenation of acetophenone.
Graphical abstractTwo Ru (II) carbonyl iodide complexes with pincer bis (carbene) ligands have been synthesized and demonstrated to be effective in the transfer hydrogenation of acetophenone by 2-propanol.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Two bis(carbene) ligands and corresponding ruthenium(II) complexes have been synthesized and characterized. ► The structures of two new complexes have been determined by X-ray crystallography study. ► Two new complexes have been proved to be efficient catalysts in the transfer hydrogenation of acetophenone.