| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1305864 | Inorganic Chemistry Communications | 2011 | 4 Pages |
Abstract
A novel mixed-valence Cu(I)/Cu(II) compound with the bridging ligand 1,4,5-triazanaphthalene (tan) is reported, having the overall formula [Cu2(tan)4](ClO4)3. The synthesis, X-ray crystal structure and preliminary spectroscopic properties are presented. The coordination of Cu(I) is tetrahedral, and that of Cu(II) is square planar. The packing of the units generates a 3D network with spaces in the cavities, available for the counter anions and accessible for small solvent molecules.
Graphical AbstractA novel mixed-valence porous Cu compound consisting of 1,4,5-triazanaphthalene bridging ligands is described.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Gerard A. van Albada, Mohamed Ghazzali, Khalid Al-Farhan, Ilpo Mutikainen, Jan Reedijk,