Article ID Journal Published Year Pages File Type
1306192 Inorganic Chemistry Communications 2009 4 Pages PDF
Abstract

We report the {W72V30} composed of 12 pentagonal {(W)W5} units and 30 [VO(H2O)]2+ linkers. This compound was characterized by the elemental analysis, thermogravimetry, X-ray diffraction analysis, spectroscopic methods (IR, UV/Vis, Raman), XPS, EPR, magnetic measurements and BVS calculations. This is the second member in the pentagonal {(W)W5}-based polyoxotungstate family.

Graphical abstractA new {W72V30} spherical cage composed of 12 pentagonal {(W)W5} moieties and 30 [VO(H2O)]2+ linkers was obtained, representing the second member in the pentagonal {(W)W5}-based polyoxotungstate family.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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