Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1306192 | Inorganic Chemistry Communications | 2009 | 4 Pages |
Abstract
We report the {W72V30} composed of 12 pentagonal {(W)W5} units and 30 [VO(H2O)]2+ linkers. This compound was characterized by the elemental analysis, thermogravimetry, X-ray diffraction analysis, spectroscopic methods (IR, UV/Vis, Raman), XPS, EPR, magnetic measurements and BVS calculations. This is the second member in the pentagonal {(W)W5}-based polyoxotungstate family.
Graphical abstractA new {W72V30} spherical cage composed of 12 pentagonal {(W)W5} moieties and 30 [VO(H2O)]2+ linkers was obtained, representing the second member in the pentagonal {(W)W5}-based polyoxotungstate family.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yan Li, Yang-Guang Li, Zhi-Ming Zhang, Qiong Wu, En-Bo Wang,