| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1306764 | Inorganic Chemistry Communications | 2007 | 4 Pages |
Abstract
Heavy Grignard reagents of strontium and barium are much more reactive than the derivatives of the lighter homologues. Ether cleavage reactions yield oxygen-centered cages such as the title compound [((thf)2BaPh2)4 · (thf)BaO], which is shown in the scheme.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Reinvestigation of the reaction of strontium and barium with iodobenzene and molecular structure of the heavy Grignard reagent [((thf)2BaPh2)4 · (thf)BaO] with an oxygen-centered square Ba5 pyramid](/preview/png/1306764.png "First Page Preview: Reinvestigation of the reaction of strontium and barium with iodobenzene and molecular structure of the heavy Grignard reagent [((thf)2BaPh2)4 · (thf)BaO] with an oxygen-centered square Ba5 pyramid")
Authors
Jens Langer, Martin Gärtner, Reinald Fischer, Helmar Görls, Matthias Westerhausen,