| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1306766 | Inorganic Chemistry Communications | 2007 | 5 Pages |
A coordination polymer [Ag4(C12H12N6)3](ClO4)4(H2O)4 (1), was achieved via the self-assembly of AgClO4 with ligand 2,5-bis(pyrazinyl)-3,4-diaza-2,4-hexadiene (L1). The structure of compound 1 is a 3D metal–organic framework that consists of the circular helicate Ag3 (L1)3 secondary building blocks (SBUs). Each Ag3L31 is capped at its every exo -monodentate pyrazinyl terminal by the unusual hexa-coordinated Ag(I) centers. Being filled within the cavities, the ClO4- anions could be exchanged reversibly with PF6- in the solid state.
Graphical abstractA three-dimensional coordination polymer [Ag4(C12H12N6)3](ClO4)4(H2O)5 (1), was achieved via the self-assembly of AgClO4 with ligand 2,5-bis(pyrazinyl)-3,4-diaza-2,4-hexadiene (L1). The anion-exchange behavior was detected for the compound 1 and it was confirmed that anion-exchange could reversibly occur between ClO4- and PF6-.Figure optionsDownload full-size imageDownload as PowerPoint slide
