Article ID Journal Published Year Pages File Type
1306791 Inorganic Chemistry Communications 2007 4 Pages PDF
Abstract
In this article, a Cu(I)-halide complex [Cu(II)Cu(I)3(1,10′-phen)Cl5]n (1) has been synthesized under hydrothermal reaction conditions. Complex 1 is a three-dimensional supramolecular network composed by one-dimensional chain-like structure. To our interest, in the chain, there exist Cu6Cl6 building unit, which is seldom found in Cu(I)-halide complex. Furthermore, the Cu6Cl6 building unit is extended by Cu(II)(1,10′-phen)Cl2 unit. Complex 1 exhibits strong luminescent property at room temperature.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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