Article ID Journal Published Year Pages File Type
1335252 Polyhedron 2008 6 Pages PDF
Abstract

Two approaches to the formation of ruthenium(II) complexes containing ligands with conjugated 2,2′:6′,2″-terpyridine (tpy), alkynyl and bithienyl units have been investigated. Bromination of 4′-(2,2′-bithien-5′-yl)-2,2′:6′,2″-terpyridine leads to 4′-(5-bromo-2,2’-bithien-5′-yl)-2,2′:6′,2″-terpyridine (1), the single crystal structure of which has been determined. The complexes [Ru(1)2][PF6]2 and [Ru(tpy)(1)][PF6]2 have been prepared and characterized. Sonogashira coupling of the bromo-substituent with (TIPS)CCH did not prove to be an efficient method of preparing the corresponding complexes with pendant alkynyl units. The reaction of 4′-ethynyl-2,2′:6’,2″-terpyridine with 5-bromo-2,2′-bithiophene under Sonogashira conditions yielded ligand 2, and the heteroleptic ruthenium(II) complex [Ru(2)(tpy)][PF6]2 has been prepared and characterized.

Graphical abstractTwo approaches to the formation of ruthenium(II) complexes containing ligands with conjugated 2,2′:6′,2″-terpyridine (tpy), alkynyl and bithienyl units are described, starting with either 4′-(2,2′- bithien-5′-yl)-2,2′:6′,2″-terpyridine or 4′-ethynyl-2,2′:6′,2″-terpyridine. The single crystal structure of 4′-(5-bromo-2,2’-bithien-5′-yl)-2,2′:6′,2″-terpyridine is reported.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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