Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1335849 | Polyhedron | 2016 | 5 Pages |
Abstract
A new diruthenium compound, Ru2(η2-DmAniF)2(μ-DmAniF)2(OAc)(O) (1), where DmAniF is N,N′-di(m-methoxyphenyl)formamidinate, was isolated as a secondary product from the reaction between Ru2(DmAniF)3(OAc)Cl and K2CO3, and its formulation was established using both single crystal X-ray diffraction and high resolution mass-spectrometry techniques. Compound 1 has an S = 3/2 ground state, and exhibits an unusually large zero-field splitting (D = 308 cm−1) as revealed by the measurement of temperature dependent magnetism.
Graphical abstractA new diruthenium compound Ru2(η2-DmAniF)2(μ-DmAniF)2(OAc)(O) was isolated and interesting structural and magnetic properties were revealed.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Stacey R. Opperwall, Bin Liu, Alice L. Pilo, Zhi Cao, Phillip E. Fanwick, Tong Ren,