Article ID Journal Published Year Pages File Type
1336783 Polyhedron 2013 9 Pages PDF
Abstract
Diverse complexation modes could be observed in group IV complexes supported by tBu-ended ansa-bis(amidine) SiMe2[N(H)C(Ph)N(tBu)]2. Two different forms were crystallized from dichloromethane and toluene, respectively. The transformation was driven by the different polarity of the solvents. With methylaluminoxane, some complexes were active in catalyzing ethylene polymerization.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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