Coordination chemistry of bidentate phosphine ligands with hydrogen-bonding arms: Picket-fence rhodium complexes

A bidentate phosphine ligand with two amide arms, designed to form hydrogen bonds with electron-donating moieties, was synthesized and isolated in high diastereomeric excess (95% de). The hydrogen-bonding abilities of the ligand and its diastereomer were demonstrated with two rhodium complexes containing these ligands. The structures of the rhodium compounds are reminiscent of the well-studied picket-fence porphyrin systems.

Graphical abstractA bidentate phosphine ligand with two amide arms, designed to form hydrogen bonds with electron-donating moieties, was synthesized and isolated in high diastereomeric excess (95% de). The hydrogen-bonding abilities of the ligand and its diastereomer were demonstrated with two ligand-containing rhodium complexes. The structures of the rhodium compounds are reminiscent of the well-studied picket-fence porphyrin systems.Figure optionsDownload full-size imageDownload as PowerPoint slide