Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1366977 | Bioorganic & Medicinal Chemistry Letters | 2007 | 5 Pages |
Abstract
Continuing search for beneficial additive toward the Beckmann rearrangement (BR) of indanone oxime has revealed that common Lewis acid catalyst in methanesulfonyl chloride (MsCl) showed increasing efficiency in this ionic rearrangement. The new protocol with MsCl is superior to the classical phosphorus-based methods such as PPA and Eaton reagent, especially in the reaction of indanone oximes.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yasuhiro Torisawa, Takao Nishi, Jun-ichi Minamikawa,