Gallium(III) complexes of methyl pyropheophorbide-a as synthetic models for investigation of diastereomerically controlled axial ligation towards chlorophylls

Gallium(III) chlorins possessing a series of axial ligands were synthesized as model compounds of natural chlorophylls. A pair of diastereomers arising from the fifth axial coordination onto the asymmetric chlorin π-macrocycle could be discriminated in a solution by both 1H- and 13C NMR spectroscopies.

Graphical abstractA pair of diastereomeric Ga(III) chlorophyll derivatives 1–4 arising from the fifth axial coordination onto the asymmetric chlorin π-macrocycle could be discriminated by NMR spectroscopy in solution.Figure optionsDownload full-size imageDownload as PowerPoint slide