Article ID Journal Published Year Pages File Type
146857 Chemical Engineering Journal 2015 8 Pages PDF
Abstract

•The Mg–Fe–La trimetal composite was prepared by a facile co-precipitation method.•The as-prepared adsorbents were synthesized at room temperature (25 °C).•The maximum adsorption capacity for fluoride of the as-prepared material was 112.17 mg/g.•Langmuir and pseudo-second-order kinetic models were used to fit the adsorption process.

Flaky Mg–Fe–La trimetal composite as an adsorbent for fluoride removal was successfully synthesized by a facile co-precipitation method in this study. Various reaction parameters such as Mg/Fe/La molar ratio, synthesis temperature and calcination temperature were studied. The as-prepared adsorbents were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FT-IR), energy-dispersive X-ray spectroscopy (EDS) and Brunauer–Emmett–Teller (BET). The experimental results demonstrated that the adsorbent with a Mg/Fe/La molar ratio of 25:1:4, synthesized at room temperature (25 °C) and calcined at 400 °C, obtained the largest adsorption capacity of 112.17 mg/g for fluoride at near neutral pH. The BET surface area and average pore diameter of the adsorbent were 178.55 m2/g and 31.16 nm, respectively. The adsorption process was fitted well with the Langmuir isotherm and pseudo-second-order kinetic model. The adsorption mechanisms for fluoride were adsorption/complexation and ion exchange interaction. Based on the experimental results, the flaky Mg–Fe–La composite can be a very promising material for fluoride removal from aqueous solution.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
Authors
, , , , ,