Graphite and graphene oxides catalyze bromination or alkylation in reaction of phenol with t-butylbromide

Graphite and graphene oxides, prepared using pure graphite with nitric acid by the Hammers method and followed by rapid heating, were used as a catalyst for bromination or alkylation. The activity test was performed in a batch reactor for 5 h at 323 K with phenol and tert-butylbromide as the raw materials. The relationships between the structures and compositions of the graphite and graphene oxides and catalytic activities were studied. The structure and composition of the graphene oxide were analyzed by XRD and X-ray photoelectron spectroscopy. The phenol bromination mainly occurred on the graphite oxide accompanied by Friedel–Crafts alkylation that occurred during the initial stage. The bromination occurred on the carbonyl group in the layers of the graphite oxide based on the XPS and XRD analyses. The mechanism of the phenol bromination on the graphite oxide is discussed.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights• Graphite and graphene oxides catalyze bromination of phenol with tert-butylbromide. • The bromination occurs on the carbonyl group in the layers of the graphite oxides. • Prepared using graphite with nitric acid, KMnO4/H2SO4 and followed by rapid heating. • The alkylation occurs during the initial stage and slightly during the reaction.