Article ID Journal Published Year Pages File Type
149822 Chemical Engineering Journal 2012 9 Pages PDF
Abstract

In this work, the mesoporous-assembled TiO2–NiO mixed oxide nanocrystals were successfully synthesized by a sol–gel process with the aid of a structure-directing surfactant under mild conditions. The photocatalytic activity of the synthesized mixed oxide nanocrystals for degradation of Methyl Orange (MO) azo dye used as a model wastewater contaminant was investigated under UV light irradiation. The synthesized mixed oxide nanocrystals were systematically characterized by TG-DTA, N2 adsorption–desorption analysis, SEM-EDX, XRD, and UV–visible spectroscopy. The photocatalytic activity results showed that the incorporation of NiO phase with a suitable content into the TiO2–NiO mixed oxide increased the photocatalytic MO degradation efficiency. It was found that the mesoporous-assembled Ti75–Ni25 mixed oxide nanocrystal (with 75 mol % TiO2 and 25 mol % NiO) provided a maximum MO degradation efficiency as compared to the other investigated nanocrystals as well as the commercial P-25 TiO2 powder. The induced n–p junction at the interfacial contact between the TiO2 and NiO phases in the Ti75–Ni25 mixed oxide nanocrystal is supposed to efficiently prevent the electron–hole recombination upon the UV light excitation and consequently enhance its photocatalytic degradation activity.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Mesoporous-assembled TiO2–NiO mixed oxide nanocrystals by a sol–gel process. ► Synthesized TiO2–NiO mixed oxide nanocrystals had narrow pore size distribution. ► Ti75–Ni25 mixed oxide nanocrystal showed high photocatalytic degradation activity. ► Induced n–p junction enhanced photocatalytic activity of Ti75–Ni25 mixed oxide.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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