Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5148933 | Journal of Power Sources | 2017 | 10 Pages |
Abstract
Na3V2(PO4)3 (NVP) is a very promising cathode material in sodium ion battery for rapidly emerging large-scale energy storage with its classical 3D NASCION structure. However, the cycling life and rate performances are restricted its low electronic conductivity. To overcome these, the double carbon-wrapped Na3V2(PO4)3 composite is firstly designed through rheological phase approach, delivering enhanced electrochemical properties. The unique double carbon layers are composed of uniform amorphous carbons as protecting framework for stabilizing the structure, as well as the graphitized carbon sheets playing the role of conductive network for better electronic conductivity. This double carbon-wrapped Na3V2(PO4)3 composite exhibits a high reversible capacity of 99.8 mAh gâ1 over 500 cycles at 1Â C (110Â mAÂ gâ1), yielding the coulombic efficiency of â¼99.8%. Meanwhile, it displays an initial capacity of 73 mAh gâ1Â at 100Â C and remains 55 mAh gâ1Â at an ultra-rate of 200Â C. Even after cycling at 200Â C over 12Â 000 cycles, the Na+-storage capacity of 40 mAh gâ1 with a retention of 72.7% is still obtained, highlighting its excellent long cycling life and remarkable rate performances.
Related Topics
Physical Sciences and Engineering
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Authors
Sijie Li, Peng Ge, Chenyang Zhang, Wei Sun, Hongshuai Hou, Xiaobo Ji,