Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5151273 | Inorganic Chemistry Communications | 2017 | 14 Pages |
Abstract
Three copper(I) cyanide coordination polymers were constructed based on two flexible N-heterocyclic ligands. [Cu8(CN)8(btmb)2]n (1) is a 2D double-layered network containing eight distinct Cu(I) centers and eight μ2-cyanides. Complex 2 shows a ladder-like chain structure, while complex 3 exhibits a 2D wave-like network. These Cu(I) complexes are stable up to 270-300 °C and emit blue luminescence.208
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Li-Ruo Lu, Min Shao, Zhao-Xi Wang, Xiang He, Ming-Xing Li,