Article ID Journal Published Year Pages File Type
5151273 Inorganic Chemistry Communications 2017 14 Pages PDF
Abstract
Three copper(I) cyanide coordination polymers were constructed based on two flexible N-heterocyclic ligands. [Cu8(CN)8(btmb)2]n (1) is a 2D double-layered network containing eight distinct Cu(I) centers and eight μ2-cyanides. Complex 2 shows a ladder-like chain structure, while complex 3 exhibits a 2D wave-like network. These Cu(I) complexes are stable up to 270-300 °C and emit blue luminescence.208
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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