Excluded volume effect on the electrophoretic mobility of colloidal particles

In a recent work [J. Colloid Interface Sci. 316 (2007) 196] we studied the influence of the excluded volume effect on spatial distributions of ionic species and electrostatic potential in the neighborhood of a suspended spherical particle. It was shown that the excluded volume effect considerably increases the surface potential (for a given value of the particle charge) as compared to the case when ideal ion behavior is assumed. In the present work we extend our previous equilibrium results to the perturbed/nonequilibrium problem and analyze the effect of ion size constraints on the electrophoretic mobility of a rigid spherical particle immersed in a general electrolyte solution. We find that the electrophoretic mobility always increases with the excluded volume effect, which might broaden the range of experimental data that can be interpreted, including those cases where the measured mobility exceeded the theoretical maximum value predicted by the standard model.

Graphical abstractThe excluded volume effect (cmax)(cmax) always increases the electrophoretic mobility as compared to the case when ideal ion behavior is assumed (standard model). This fact extends the range of experimental data that can be interpreted, including those cases where the measured mobility exceeded the theoretical maximum value predicted by the standard model.Figure optionsDownload full-size imageDownload as PowerPoint slide