Article ID Journal Published Year Pages File Type
6464988 Chemical Engineering Journal 2018 7 Pages PDF
Abstract

•CoS2/C assembled by CoS2 nanoparticles anchored on spongy carbon is presented.•As anode materials for LIBs/SIBs, the composite shows good performances.•This synthesis route can be used to synthesize other metal sulfides composite.

A spongy CoS2/carbon composite assembled from CoS2 nanoparticles (∼20 nm) homogeneously anchored on a spongy carbon matrix was synthesized through a facile freeze-drying method and a hydrothermal process. As anode material for lithium/sodium ion batteries (LIBs/SIBs), this composite shows significantly enhanced lithium/sodium storage performance with the synergetic effects due to the electrical conductivity of the carbon matrix and the porous structure, which provide buffer spaces for volume expansion during charge/discharge processes and feasible transfer pathways for electrons/ions. The electrochemical results demonstrate that the spongy CoS2/carbon composite is an outstanding anode material for LIBs and SIBs. It delivers a high specific capacity of 610 mAh g−1 at 500 mA g−1 after 120 cycles in LIBs and 330 mAh g−1 at 500 mA g−1 after 60 cycles in SIBs, respectively. Moreover, the freeze-drying/hydrothermal process developed in this work could be useful for the construction of many other high-capacity metal sulfide composites as electrode materials for sodium ion batteries.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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