Article ID Journal Published Year Pages File Type
6465037 Chemical Engineering Journal 2017 10 Pages PDF
Abstract

•Au@Pt-nFs/GO was synthesized through a facile and green one-pot method.•Au@Pt-nFs/GO exhibit open structure with large surface area and abundant active site.•Au@Pt-nFs/GO was employed to fabricate nonenzymatic N2H4 sensor.•Au@Pt-nFs/GO reduced the overpotential and accelerated kinetics of N2H4 oxidation.•Au@Pt-nFs/GO exhibit highly sensitive and selective detection of N2H4.

A novel strategy is developed to synthesize three-dimensional porous Au@Pt core-shell nanoflowers supported on GO (Au@Pt-nFs/GO) for enhanced electrochemical sensing of hydrazine (N2H4). Au@Pt-nFs/GO nanocomposite was synthesized through a facile and green method, where ascorbic acid and chitosan were employed as the reductant and linking agent, respectively. The experiment results revealed that a large numbers of Au@Pt-nFs with Au cores and Pt dendritic shells were distributed on the surface of GO sheets. Meanwhile, Au@Pt-nFs/GO with large surface area, abundant active sites and open structure reduced the overpotential and accelerated kinetics of N2H4 oxidation, therefore making the sensor based on Au@Pt-nFs/GO exhibit an excellent performance for N2H4 analysis with a wide linear range of 0.8 μM-0.429 mM, a high sensitivity of 1695.3 μA mM−1 cm−2 and a low detection limit of 0.43 μM (S/N = 3). Moreover, the sensor also exhibited good selectivity, repeatability and stability. Application of the sensor for the detection of N2H4 in tap water samples was demonstrated.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
Authors
, , ,