Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6578345 | Chemical Engineering Journal | 2018 | 9 Pages |
Abstract
This study develops and evaluates a novel wet method for NO removal using a Na2S2O8/CaO2 solution. The effects of these two components both and alone in solution, Na2S2O8 concentration, CaO2 concentration, initial pH, reaction temperature, and the concentrations of NO and O2 on NO removal efficiency were evaluated using a bubbling reactor. The combination of Na2S2O8 and CaO2 had a synergistic effect on NO removal efficiency. NO removal was effected by CaO2 concentration, reaction temperature and the initial solution pH, while Na2S2O8 concentration and O2 concentration had little effect. The NO removal efficiency decreased linearly from 94.5 % to 75.1 % when the NO concentration increased from 139 to 559â¯ppm. The products were characterized using XRD, XPS and IC, and CaSO4·2H2O, NO3â and SO42â were found to be the main products. The EPR analysis showed that free radicals of O2â, SO4â and OH were the key species involved in the NO removal process. Finally, the corresponding reaction mechanisms were proposed.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Zhiping Wang, Yanguo Zhang, Zhongchao Tan, Qinghai Li,