Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6579287 | Chemical Engineering Journal | 2018 | 27 Pages |
Abstract
Si is considered as the most promising anode material for lithium ion batteries (LIBs) because of the high specific capacity (3579â¯mAhâ¯gâ1). However, the huge volume changes (>300%) causes structural cracking and unstable solid state electrolyte (SEI) film, leading to fast capacity fading. Herein, TiO2 coated Si/C-interconnected microsphere (Si/C@TiO2) with dual-protection is designed and fabricated via a two-step procedure. In this composite, the inner flexible carbon and outer rigid TiO2 layer work together to maintain the structural integrity, stabilize the SEI film, and enhance the conductivity of the anode composite. As a result, the obtained Si/C@TiO2 composite delivers a reversible capacity of 1077.3â¯mAâ¯hâ¯gâ1 at 0.2â¯Aâ¯gâ1 after 100 cycles, capacity retention of 58.4% at even 10â¯Aâ¯gâ1, and improved coulombic efficiency. In addition, a full cell consisted of Si/C@TiO2 anode and LiCoO2 cathode exhibits a reversible capacity of 1048â¯mAhâ¯gâ1 at 0.2â¯Aâ¯gâ1 and 820â¯mAhâ¯gâ1 at 1.5â¯Aâ¯gâ1 based on the anode active material with a working potential beyond 3.1â¯V.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Zheng Yi, Ning Lin, Tianjun Xu, Yitai Qian,