Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6587728 | Chemical Engineering Journal | 2013 | 7 Pages |
Abstract
In this paper, the comparison study of photocatalytic oxidation properties of TiO2 and ZnO-quantum dots (QDs) in gaseous phase was designed and performed to degrade acetaldehyde (CH3CHO) first time. The obtained results showed that the 1st order rate constant for the prepared QDs of ZnO (1.9Â ÃÂ 10â2/min) is one magnitude higher than that of Degussa P-25 (8.3Â ÃÂ 10â3/min). The efficiencies were found to be 70% and 92% for Degussa P-25 and ZnO-QDs respectively in 120Â min of reaction time. The QDs were prepared from zinc nitrate hexahydrate (Zn(NO3)â
6H2O), n-propylamine and SDS surfactant in 6Â h refluxing. The crystallinity of the product was analyzed with X-ray diffraction (XRD) and it reveals that prepared QDs size is very small and it exhibit wurzite phase. The general morphology of prepared QDs were observed with using FESEM and TEM, which showed that the average size are in the range of â¼6-7Â nm. The elemental and compositional analysis was also carried out with FTIR spectroscopy.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Rizwan Wahab, Suraj Kumar Tripathy, Hyung-Shik Shin, Mamata Mohapatra, Javed Musarrat, Abdulaziz A. Al-Khedhairy, Nagendra Kumar Kaushik,