Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7725819 | Journal of Power Sources | 2018 | 11 Pages |
Abstract
CO/CO2 are the major gas reactant/product in the fuel electrode of reversible solid oxide cells (RSOC). This study proposes a two-charge-transfer-step mechanism to describe the reaction and transfer processes of CO-CO2 electrochemical conversion on a patterned Ni electrode of RSOC. An elementary reaction model is developed to couple two charge transfer reactions, C(Ni)+O2â(YSZ) â CO(Ni)+(YSZ) +2eâ and CO(Ni)+O2â(YSZ) â CO2(Ni)+(YSZ)+2eâ, with adsorption/desorption, surface chemical reactions and surface diffusion. This model well validates in both solid oxide electrolysis cell (SOEC) and solid oxide fuel cell (SOFC) modes by the experimental data from a patterned Ni electrode with 10â¯Î¼m stripe width at different pCO (0-0.25â¯atm), pCO2 (0-0.35 atm) and operating temperature (600-700 °C). This model indicates SOEC mode is dominated by charge transfer step C(Ni)+O2â(YSZ)âCO(Ni)+(YSZ) +2eâ, while SOFC mode by CO(Ni)+ O2â(YSZ)âCO2(Ni)+(YSZ)+2eâ on the patterned Ni electrode. The sensitivity analysis shows charge transfer step is the major rate-determining step for RSOC, besides, surface diffusion of CO and CO2 as well as CO2 adsorption also plays a significant role in the electrochemical reaction of SOEC while surface diffusion of CO and CO2 desorption could be co-limiting in SOFC.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Yu Luo, Yixiang Shi, Wenying Li, Ningsheng Cai,