Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7728056 | Journal of Power Sources | 2016 | 7 Pages |
Abstract
The impact of Nafion on the oxygen reduction reaction (ORR) activity is studied for Pt/C and Pt-alloy/C catalysts using thin-film rotating disk electrode (TF-RDE) methods in 0.1Â M HClO4. Ultrathin uniform catalyst layers and standardized activity measurement protocols are employed to obtain accurate and reproducible ORR activity. Nafion lowers the ORR activity which plateaus with increasing loading on Pt catalysts. Pt particle size is found not to have significant influence on the extent of the SA decrease upon Nafion incorporation. Catalysts using high surface area carbon (HSC) support exhibit attenuated activity loss resulting from lower ionomer coverage on catalyst particles located within the deep pores. The impact of metallic composition on the activity loss due to Nafion incorporation is also discussed.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Kazuma Shinozaki, Yu Morimoto, Bryan S. Pivovar, Shyam S. Kocha,