Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7729971 | Journal of Power Sources | 2016 | 9 Pages |
Abstract
In this contribution, the novel 2D sandwich-like NiO/C arrays on Ti foil are successfully designed and fabricated for the first time via simple and controllable hydrothermal process. In this strategy, we use green glucose as carbon source and ultrathin Ni(OH)2 nanosheet arrays as precursor for NiO nanoparticles and sacrificial templates for coupled graphitized carbon layers. This advanced sandwiched composite can not only provide large surface area for numerous active sites and continuous contact between active materials and electrolyte, but also protect the active nanoparticles from aggregation, pulverization and peeling off from conductive substrates. Furthermore, the porous structure derived from lots of substances loss under high-temperature calcinations can effectively buffer possible volume expansion and facilitate ion transfer. In this article, sandwiched NiO/C arrays, utilized as anode for LIBs, demonstrated high specific capacity (â¼1458 mAh gâ1 at 500 mA gâ1) and excellent rate performance and cyclablity (â¼95.7% retention after 300 cycles).
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Yangyang Feng, Huijuan Zhang, Wenxiang Li, Ling Fang, Yu Wang,