Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7734672 | Journal of Power Sources | 2015 | 9 Pages |
Abstract
In this work experimental results are presented and analyzed for catalytic platinum films of ultra-low thickness of 0.09-3.47 nm and Pt loading of 0.18-7.44 μg cmâ2 deposited using the PLD method with an ArF excimer laser (λ = 193 nm) at room temperature. For Pt deposited on the surface of the Nafion® membrane (electrolyte), in a fuel cell with PLD Pt working as oxygen cathode the peak power density is obtained equal to 59.36 mW cmâ2 for the Pt loading of 1.24 μg cmâ2. In the case of Pt deposition on the gas-diffusion layer (as cathode), a much higher maximum power density of 106.36 mW cmâ2 at the same loading and a maximum of 188.44 mW cmâ2 at the 7.44 μg cmâ2 loading is observed. Experiments are also presented of Nafion® modification before the deposition of Pt on the Nafion®, in which the surface of the membranes is enlarged by bombarding with Ar ions from a plasma generator of RF 13.56 MHz. The electrochemical activity of the elements prepared by PLD is assessed in a H2/Pt/Nafion®/Pt/O2 PEMFC. The structure and morphology of the surface layers is examined by AFM and SEM microscopy.
Related Topics
Physical Sciences and Engineering
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Authors
Waldemar Mróz, BogusÅaw Budner, Wojciech Tokarz, Piotr Piela, Michael L. Korwin-Pawlowski,