Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7734732 | Journal of Power Sources | 2015 | 7 Pages |
Abstract
Submicron-structured Li3V2(PO4)3/C has been synthesized by carbon-thermal reduction method with poly(acrylic acid) and d-(+)-glucose as carbon sources. The pure monoclinic structure of Li3V2(PO4)3/C has been confirmed by XRPD and Rietveld refinement, scanning electron microscopy, and transmission electron microscopy. The specific capacity of Li3V2(PO4)3/C as cathode has been evaluated, between 3.0 and 4.3 V vs Li+/Li, in the two different electrolytes: 1 M solution of LiPF6 in EC:DMC (1:1) at room temperature and in EC:DMC:DEC (1:1:1) at low temperature (0 and â20 °C). Because of the submicron-size dimensions of Li3V2(PO4)3 and of the good carbon coating, the material discharge capacities as high as 103, 98 and 81 mAh gâ1 at 40, 60 and 100C rates, retains 93% of the initial discharge capacity after 1000 cycles at 100C. The performances even at low temperature are also good with values of the order of 84, 40, 23, 19 mAh gâ1 at 0 °C and 69, 24, 19, 15 mAh gâ1 at â20  °C at 3, 7.5, 15, 30 C-rates, respectively.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
M. Secchiaroli, F. Nobili, R. Tossici, G. Giuli, R. Marassi,