Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7738543 | Journal of Power Sources | 2014 | 6 Pages |
Abstract
Higher ion exchange capacity (IEC) and proton conductivity of the hybrid material (one order of magnitude higher for the functionalized filler) reflected in superior performance of Nafion/TiO2-RSO3H composite membranes compared to Nafion. The highest conductivity value was obtained for the composite membrane containing 10 wt. % TiO2-RSO3H (Ï = 0.08 S cmâ1 at 140 °C). The membranes were tested in a DMFC single cell. The presence of the filler resulted in a general enhancement in the cell response, in terms of both higher power density (PD) delivered and lower methanol crossover with respect to unfilled Nafion membrane. The DMFC containing N_10TiO2-RSO3H membrane showed the best performance at 110 °C with a PD of 64 mW cmâ2, corresponding to a PD improvement of about 40% with respect to that of Nafion membrane.
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Authors
Dafne Cozzi, Catia de Bonis, Alessandra D'Epifanio, Barbara Mecheri, Ana C. Tavares, Silvia Licoccia,