Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7738585 | Journal of Power Sources | 2014 | 4 Pages |
Abstract
One diazonium (perfluoroalkyl) benzenesulfonimide monomer, perfluoro-3, 6-dioxa-4-methyl-7-octene benzenesulfonyl imide, has been synthesized from Nafion monomer for the first time. With trifluorovinyl ether and diazonium precursors, the partially-fluorinated diazonium PFSI monomer can be polymerized and will provide chemically bonding with carbon electrode in proton exchange membrane fuel cells. A systematic study of the synthesis and characterization of this diazonium PFSI monomer has been conducted by varying reaction conditions. The optimized synthesis method has been established in the lab.
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Authors
Hua Mei, Dan D'Andrea, Tuyet-Trinh Nguyen, Chima Nworie,