Article ID Journal Published Year Pages File Type
7742917 Journal of Power Sources 2012 5 Pages PDF
Abstract
► In situ Raman spectroscopy of layered solid solution of Li2MnO3-LiMO2 (M = Ni, Mn, and Co). ► Impedance decrease steadily and reaches minimum at 4.47 V ► Less steep increase in impedance as cell voltage traversed the first charge 4.5 V plateau. ► Lithium extraction occur from transition metals as well as lithium layers in 4.1-4.4 V voltage range. ► Extraction of oxygen along with lithium ions from the transition metal layers takes place after 4.5 V.
Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
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