| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7743109 | Journal of Power Sources | 2012 | 6 Pages |
Abstract
⺠Sr-free Nd1.95NiO4+d cathode composition does not prevent from Cr-poisoning in SOFC. ⺠Electrochemical reduction of CrVIg to CrIIIs on Nd-nickelate induces Cr-poisoning. ⺠Si contamination in Nd1.95NiO4+d leads to insulating Nd-silicate formation. ⺠At the interface of Nd1.95NiO4+d with Ce0.9Gd0.1O1.95 an Nd-cerate reaction layer is formed. ⺠Secondary Nd-phase formations trigger Nd-nickelate decomposition into NiO.
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Authors
J. Andreas Schuler, Henning Lübbe, Aïcha Hessler-Wyser, Jan Van herle,