| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7748416 | Inorganic Chemistry Communications | 2018 | 5 Pages |
Abstract
A series of 3D MOFs encapsulating functional macrocyclic metal complexes were obtained from the simple one-step solvothermal reaction of zinc nitrate or copper nitrate, benzentricarboxylate (BTC) and certain macrocyclic metal complexes. In the Zn-BTC or Cu-BTC-based frameworks, the coordinatively unsaturated metal centers of macrocylic metal complexes can increase capacity of hydrogen adsorption. It has provided a new strategy for the orientated construction of new crystalline functional hybrid materials and for the rational design of exposed metal centers.302
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yu Li, Xun-Zhong Zou, Wen-Da Qiu, Ao You, Ze-Ming Zhang, An-Sheng Feng, Xiao-Ling Chen,