Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7748449 | Inorganic Chemistry Communications | 2018 | 18 Pages |
Abstract
Successive chirality transformation for coordination compounds of the V-shaped ligand 3-aminobenzoic acid was observed in different solvents with different polarities: cyclohexanol (non-helical achiral chain)Â <Â n-propyl alchohol (non-helical achiral chain)Â <Â ethanol (helical homochiral MOF)Â <Â dimethyl acetamide (helical homochiral MOF)Â <Â DMF (helical homochiral MOF)Â <Â DMSO (helical achiral chain)Â <Â water (helical achiral chain). Moreover, significantly different photoluminescence of two isomeric compounds with different chirality was discovered.120
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ming-Xiu Du, Ming-Sheng Wang, Guo-Cong Guo,