Article ID Journal Published Year Pages File Type
7748449 Inorganic Chemistry Communications 2018 18 Pages PDF
Abstract
Successive chirality transformation for coordination compounds of the V-shaped ligand 3-aminobenzoic acid was observed in different solvents with different polarities: cyclohexanol (non-helical achiral chain) < n-propyl alchohol (non-helical achiral chain) < ethanol (helical homochiral MOF) < dimethyl acetamide (helical homochiral MOF) < DMF (helical homochiral MOF) < DMSO (helical achiral chain) < water (helical achiral chain). Moreover, significantly different photoluminescence of two isomeric compounds with different chirality was discovered.120
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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