| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7748812 | Inorganic Chemistry Communications | 2017 | 16 Pages |
Abstract
A new Cu(II) coordination polymer (1) constructed from an axially chiral heterocyclic spiro ligand, 2,4,8,10-tetraoxaspiro[5,5]undecane-3,9-dicarboxylic acid (H2L) and 1,3-bis(4-pyridyl)propane (bpp), has been prepared and characterized. Structural analysis shows that 1 features a 2D undulated layer of rhombic meshes with (4, 4) topology. Interestingly, a 1D wave-like water tape formed by the cyclic centrosymmetric chairlike octamer water clusters (H2O)8 are observed between the 2D sheets. Furthermore, the experimental data and computational studies of superoxide dismutase (SOD) activity of H2L and 1 were investigated.106
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yi-Fan Kang, Xiqiang Liang, Xiao Wang, Tiantian Si, Yitong Chen, Jianhua Zhang, Jing Zhao,