| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7749456 | Inorganic Chemistry Communications | 2014 | 4 Pages |
Abstract
The first metal-organic 5-nitrotetrazolate, [Me3Sn(μ-OH)SnMe3(μ-OH)SnMe3(H2O)][NT] (2), has been prepared. X-ray diffraction revealed the presence of the trinuclear [Me3Sn(μ-OH)SnMe3(μ-OH)SnMe3(H2O)]+ cation to which the 5-nitrotetrazolate anion is coordinated via a ring-N atom. Compound 2 is highly sensitive to impact and can be classified as a primary explosive.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis, supramolecular structure, and energetic properties of the first metal-organic nitrotetrazolate, [Me3Sn(μ-OH)SnMe3(μ-OH)SnMe3(H2O)][NT] (NT = 5-nitrotetrazolate)](/preview/png/7749456.png "First Page Preview: Synthesis, supramolecular structure, and energetic properties of the first metal-organic nitrotetrazolate, [Me3Sn(μ-OH)SnMe3(μ-OH)SnMe3(H2O)][NT] (NT = 5-nitrotetrazolate)")
Authors
Gesine Stock, Cristian G. Hrib, Raik Deblitz, Marcel Kühling, Georg Plenikowski, Frank T. Edelmann,