Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7749500 | Inorganic Chemistry Communications | 2014 | 4 Pages |
Abstract
With [Zn(L)(MeCN)] (H2L = N,Nâ²-bis(3-methoxy-salicylidene)cyclohexane-1,2-diamine) as the precursor,  series of mixed anion-induced luminescent Zn2Ln3 complexes [Zn2(L)3Cl2(μ2-OH)(μ3-OH)2Ln3(N3)2] (Ln = La, 1; Ln = Nd, 2; Ln = Yb, 3; Ln = Er, 4 or Ln = Gd, 5) are obtained, respectively, where transmetallation of the partial precursor leads to the coexistence of two Zn2 + ions and one Ln3 + ion in the inner cis-N2O2 core and the other two Ln3 + ions in the outer O2O2 moieties of three deprotonated ligands.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Heini Feng, Zhao Zhang, Weixu Feng, Peiyang Su, Xingqiang Lü, Daidi Fan, Wai-Kwok Wong, Richard A. Jones, Chengyong Su,