| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7749674 | Inorganic Chemistry Communications | 2014 | 4 Pages |
Abstract
A novel ruthenium(II) complex 1 has been structurally characterized including a nonchiral ligand Lb formed from a chiral bis-Schiff-base compound with two stereogenic centers derived from D- or L-phenylalanine. In the process of Ru(II) ion complexation, a unique rearrangement takes place for ligand Lb involving the proton migration to cause the shift of a CÂ =Â N double bond accompanied by the disappearance of a chiral center.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Jiao Geng, Kun Zhang, Yu-Xin Peng, Li Wang, Wei Huang,