Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9760138 | Journal of Power Sources | 2005 | 8 Pages |
Abstract
Solid-state electrochemical double-layer capacitors (ELDCs) based on alkaline polyvinyl alcohol (PVA) solid polymer electrolytes (SPEs) are prepared. Electrochemical capacitance performance of these capacitors is studied by cyclic voltammetry, galvanostatic charge-discharge testing, and ac impedance spectroscopy. For comparison, two types of EDLC cells are constructed and tested. It is found that an EDLC with a PVA polymer electrolyte exhibits much higher capacitance and longer cycle-life than one with the PP/PE separator. The specific capacitance for the EDLC with the PVA-based SPE is in the range of 100-112Â FÂ gâ1, and depends on the scan rate or the charge-discharge current rates. The results also indicate that the solid-state EDLC shows a relatively stable specific capacitance of 100Â FÂ gâ1 after 1000 cycles. The findings suggest that the PVA-based SPE is a promising material for use in EDLCs.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Chun-Chen Yang, Sung-Ting Hsu, Wen-Chen Chien,